Microwave Absorption and Molecular Structure in Liquids. LXV. A Precise Michelson Interferometer for Millimeter Wavelengths and the Dielectric Constants and Losses of Some Low-Loss Liquids at 2.1 mm

被引:67
作者
Garg, S. K. [1 ]
Kilp, H. [1 ]
Smyth, C. P. [1 ]
机构
[1] Princeton Univ, Frick Chem Lab, Princeton, NJ 08544 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.1697130
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The theory and apparatus for a Michelson interferometer for the precise measurement of dielectric constant and loss of liquids at 2.1-mm wavelength are described. The probable error of the dielectric-constant measurements is 0.2%. The probable error of the loss measurements is 2% or +/- 0.0002, whichever is higher. The dielectric constants and losses of dilute solutions of chlorobenzene in benzene have been measured at 2.1-mm wavelength at 20 degrees and compared in the light of existing lower-frequency data. The dielectric constants and losses of several nonpolar and slightly polar liquids have also been measured at 2.1-mm wavelength at 20 degrees. The presence of appreciable losses in benzene and carbon tetrachloride has been confirmed. Measured losses in cyclohexane and n-heptane are considerably lower than those in benzene and carbon tetrachloride.
引用
收藏
页码:2341 / 2346
页数:6
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