A PRIMITIVE MODEL FOR SINGLE-CHAIN AQUEOUS-SOLUTION BEHAVIOR OF PEO UNDER PRESSURE

被引：43

作者：

BEKIRANOV, S

BRUINSMA, R

PINCUS, P

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT MAT,SANTA BARBARA,CA 93106

[2] UNIV CALIF LOS ANGELES,DEPT PHYS,LOS ANGELES,CA 90077

来源：

EUROPHYSICS LETTERS | 1993年 / 24卷 / 03期

关键词：

D O I：

10.1209/0295-5075/24/3/005

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

A model of polymer chain conformations is introduced which strongly modifies the Flory theory by accounting for the saturation of hydrogen bonds in hydrosoluble polymers. The theory leads to an unusual pressure-dependent phase behavior, including a critical pressure beyond which hydrosolubility is reduced.

引用

页码：183 / 188

页数：6

共 23 条

[1]

[Anonymous], 1988, SCALING CONCEPTS POL

[2]

Bailey F.E.J., 1976, POLYETHYLENE OXIDE

[3] ADIABATIC COMPRESSIBILITY OF POLYMER-SOLUTIONS [J].