PREDISSOCIATION OF OXYGEN IN THE B3-SIGMA-U-STATE

被引：26
|
作者：
CHIU, SSL
CHEUNG, ASC
FINCH, M
JAMIESON, MJ
YOSHINO, K
DALGARNO, A
PARKINSON, WH
机构：
[1] UNIV GLASGOW,DEPT COMP SCI,GLASGOW G12 8QQ,SCOTLAND
[2] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG
[3] HARVARD SMITHSONIAN CTR ASTROPHYS,CAMBRIDGE,MA 02138
来源：
JOURNAL OF CHEMICAL PHYSICS | 1992年 / 97卷 / 03期
关键词：
D O I：
10.1063/1.463165
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The predissociation linewidths and level shifts of vibrational levels of three oxygen isotopic molecules O-16(2), (OO)-O-16-O-18, and O-18(2) arising from the interactions of the B (3)SIGMA(u)- state with the four repulsive states (5)PI(u), (3)SIGMA(u)+, (3)PI(u), and (1)PI(u) been calculated. A set of parameters characterizing these interactions has been determined. Good agreement between calculated and experimental predissociation widths and shifts has been obtained for all the three isotopic molecules.
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页码：1787 / 1792
页数：6
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