Extraction of uranium(VI) with binary mixtures of a quadridentate Schiff base and various neutral donors

被引：0
|
作者：
S. K. Sahu
V. Chakravortty
机构：
[1] Utkal University,Department of Chemistry
来源：
Journal of Radioanalytical and Nuclear Chemistry | 1998年 / 227卷
关键词：
Uranium; Schiff Base; Binary Mixture; Schiff; Triphenyl Phosphine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Liquid-liquid extraction of uranium(VI) with the binary mixture of quadridentate Schiff base, bis-salicylidene ethylene diamine (H2Salen) (H2A) and neutral donors viz., triphenyl arsine oxide (TPAsO), triphenyl phosphine oxide (TPPO) and tri-n-octyl phosphine oxide (TOPO) has been studied. The extraction order in the equilibrium pH range 2.5 to 5.5 is found to be bis-salicylidene ethylene diamine < bis-salicylidene ethylene diamine + triphenyl phosphine oxide < bis-salicylidene ethylene diamine + tri-n-octyl phosphine oxide < bis-salicylidene ethylene diamine + triphenyl arsine oxide. The composition of the extracted species derived from slope analysis seems to be of the type (UO2A·2TOPO) and (UO2A·2TPPO).
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页码：163 / 165
页数：2
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