catena-poly[[[bis(3-hydroxynaphthalene-2-carboxylato)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] hemihydrate]

被引:3
|
作者
Zhang, Ling-Yun
Sun, Xian-Zhong [1 ]
机构
[1] Luoyang Normal Univ, Dept Chem, Henan 471022, Peoples R China
[2] Guangdong Police Officers Coll, Dept Technol, Guangzhou 510230, Guangdong, Peoples R China
关键词
D O I
10.1107/S1600536806029667
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Zn(C11H7O3)(2)(C10H8N2)]center dot 0.5H(2)O, each Zn-II atom is coordinated by two N atoms from two 4,40-bipyridine (bpy) ligands and two carboxylate O atoms from two 3-hydroxynaphthalene-2-carboxylate (hnc) ligands in a distorted tetrahedral geometry. The bpy ligands and Zn-II atoms form one-dimensional zigzag chains running along the c axis. The hnc ligands are located on both side of the chain. The chains are assembled into layers parallel to the bc plane, which are extended into a three-dimensional network by O - H center dot center dot center dot O hydrogen bonds and pi - pi stacking interactions.
引用
收藏
页码:M2238 / M2240
页数:3
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