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B-Doped g-C3N4 Quantum Dots-Modified Ni(OH)2 Nanoflowers as an Efficient and Stable Electrode for Supercapacitors
被引:26
|作者:
Hong, Yiwen
[1
,2
]
Yang, Jingxia
[1
]
Choi, WonMook
[2
]
Wang, Jinjie
[1
]
Xu, Jingli
[1
]
机构:
[1] Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China
[2] Univ Ulsan, Sch Chem Engn, Ulsan 44610, South Korea
基金:
中国国家自然科学基金;
国家重点研发计划;
关键词:
Boron-doped g-C3N4 quantum dots;
KOH cutting;
Ni(OH)(2) nanoflowers;
supercapacitors;
impregnation method;
COMPOSITE ELECTRODES;
ENERGY TECHNOLOGIES;
CATALYTIC-ACTIVITY;
PERFORMANCE;
HETEROJUNCTION;
INTEGRATION;
EVOLUTION;
OXIDE;
D O I:
10.1021/acsaem.0c02680
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
For increasing the specific capacitance of supercapacitors, boron-doped g-C3N4 quantum dots (B-CNQDs) were synthesized by KOH cutting and further adsorbed on the surface of Ni(OH)(2) nanoflowers (B-CNQDx-Ni) by a mild impregnation method via electrostatic force. The B-CNQDx-Ni nanocomposites exhibit an increased surface area and reduced band gap energy compared with pure Ni(OH)(2), which result in a larger contact area between the electrode and the electrolyte and enhanced charge-transfer kinetics. The best B-CNQDx-Ni sample has an excellent specific capacitance of 1700 F/g at 1.5 A/g, low impedance at the alkaline conduction of 7.421 Omega, and a high stability cycling performance of 82% capacity retention after 5000 cycles, suggesting that B-CNQDx-Ni is a type of suitable electrode material used in supercapacitors.
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页码:1496 / 1504
页数:9
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