Organozinc-mediated direct cross-coupling under microwave irradiation

被引：0

作者：

Li, Chun-Jing ^{[1
]}

机构：

[1] Hebei Chem & Pharmaceut Coll, Dept Chem & Environm Engn, Shijiazhuang 050026, Hebei, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2021年 / 45卷 / 9-10期

关键词：

aryl pivalates; arylzinc reagents; C-C bond; microwave; organozinc-mediated; SINGLE-ELECTRON-TRANSFER; ARYL; REAGENTS; BOND; ACTIVATION; RADICALS; IODIDES; HALIDES; ZINC; ION;

D O I：

10.1177/17475198211026479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a direct cross-coupling reaction between (het)aryl pivalates/tosylates and di(het)arylzinc species in 2-methyltetrahydrofuran/N-methyl pyrrolidone (1:1), which occurs via C-O bond cleavage under microwave irradiation. The reaction takes place smoothly in short reaction times without the addition of any catalyst or ligand. The reaction is suitable for a broad scope of substrates and exhibits good functional group compatibility, utilizes a simple work-up procedure, and gives the desired products in high purity.

引用

页码：869 / 875

页数：7

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