Straightforward synthesis of ferrocenyl-based thioether and application as chemosensor for Hg2+ ion

被引：13
|
作者：
Teng, Qiang [1 ]
Liu, Yufeng [1 ]
Hu, Jianfeng [1 ,2 ]
Chai, Hao [1 ]
Li, Kuofei [1 ]
Zhang, Hao [1 ,2 ]
机构：
[1] Inner Mongolia Univ, Sch Chem & Chem Engn, Hohhot 010021, Peoples R China
[2] Inner Mongolia Key Lab Fine Organ Synth, Hohhot 010021, Peoples R China
来源：
TETRAHEDRON | 2016年 / 72卷 / 27-28期
基金：
美国国家科学基金会;
关键词：
Metal-free; Ferroceny; Reductive coupling; Thioether; Chemosensor; N-TOSYLHYDRAZONES; ASYMMETRIC CATALYSIS; EFFICIENT SYNTHESIS; COUPLING REACTIONS; TERMINAL ALKYNES; METAL-COMPLEXES; BOND FORMATION; ARYL IODIDES; MG2+ IONS; THIOLS;
D O I：
10.1016/j.tet.2016.05.008
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and efficient strategy of constructing ferrocene-based thioether ligands through metal-free reductive coupling of thiols with N-tosylhydrazones bearing a ferrocenyl group has been developed. This method features metal-free, good functional group tolerance, and readily available starting materials. Moreover, the compound 3k as a novel chemosensor has shown excellent recognition towards Hg2+ ion via optical and electrochemical signals. Quantification of the absorption titration analysis shows that the detection limit was 9.56x10(-7) M for 3k-Hg2+. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3890 / 3897
页数：8
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