Catalytic Asymmetric Intramolecular Hydroacylation with Rhodium/Phosphoramidite-Alkene Ligand Complexes

被引：74

作者：

Hoffman, Thomas J. ^{[1
]}

Carreira, Erick M. ^{[1
]}

机构：

[1] ETH, Organ Chem Lab, CH-8093 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 45期

关键词：

asymmetric catalysis; cyclopentanone; hydroacylation; P ligands; rhodium; CHIRAL DIENE LIGANDS; ENANTIOSELECTIVE CONJUGATE ADDITION; PHOSPHINE-OLEFIN COMPLEXES; TRANSITION-METAL CATALYSIS; PRIMARY ALLYLIC AMINES; STEERING LIGANDS; HOMOGENEOUS CATALYSIS; RHODIUM COMPLEXES; HIGH-PERFORMANCE; ORGANOSILICON COMPOUNDS;

D O I：

10.1002/anie.201104595

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Give me a P: An asymmetric intramolecular Rh-catalyzed hydroacylation reaction of pent-4-enals for the preparation of functionalized cyclopentanones in good yield and high enantioselectivity is described (see scheme, DCE=dichloroethane). This process uses rhodium complexes featuring novel modular phosphoramidite-alkene ligands and achiral phosphine coligands. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10670 / 10674

页数：5

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