Features of the Chemical Interaction of 2-Furaldehyde and 1,3,5-Trihydroxybenzene in an Alkaline Medium to Obtain a Plasticizing Additive

被引:0
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作者
Poluektova, Valentina Anatolyevna [1 ]
Cherkashina, Natalia Igorevna [1 ]
Starchenko, Sergey Aleksandrovich [1 ]
Romanyuk, Dmitriy Sergeevich [1 ]
机构
[1] Belgorod State Technol Univ, Dept Theoret & Appl Chem, Belgorod 308012, Russia
关键词
UV spectroscopy; IR spectroscopy; superplasticizer; cement composition; water-cement ratio; SUPERPLASTICIZERS; HYDRATION;
D O I
10.3390/chemengineering5040084
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The paper presents data on the study of the polycondensation of 2-furaldehyde and 1,3,5-trihydroxybenzene in an alkaline medium to obtain a plasticizing additive. Results are presented on the study of the products of the separate interaction of 1,3,5-trioxybenzene and 2-furaldehyde with NaOH, and the joint polycondensation of 1,3,5-trioxybenzene with 2-furaldehyde with NaOH by UV spectroscopy. The structure of the product of the interaction of 1,3,5-trioxybenzene with 2-furaldehyde in an alkaline medium was studied by IR spectroscopy. Stronger C-H bonds appear in the IR spectrum and stretching vibrations of the C = O group are not observed, which confirms the production of a new compound. The optimal dosage of the developed plasticizing additive has been established as 0.3% of the cement mass (calculated on dry matter). The developed plasticizing additive can significantly reduce the water-cement ratio while maintaining the strength characteristics of cement compositions. In addition, when using the additive, the strength characteristics are significantly increased with a reduced water-cement ratio.
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页数:13
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