SrxTi1-xCoO3±δ Perovskite-like Catalysts with Enhanced Activity for Hydrogen Production

被引：2
|
作者：
Liu, Yan [1 ]
Li, Huigu [1 ]
Huang, Jia [1 ]
Hu, Xiaomin [1 ]
Zhang, Yu [1 ]
Huang, Lihong [1 ,2 ]
机构：
[1] Chengdu Univ Technol, Dept Chem & Pharmaceut Engn, Chengdu 610059, Peoples R China
[2] Indiana Univ Purdue Univ Indianapolis, Richard G Lugar Ctr Renewable Energy, Indianapolis, IN 46202 USA
来源：
CHEMICAL ENGINEERING & TECHNOLOGY | 2021年 / 44卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Acetic acid; Autothermal reforming; Hydrogen production; Perovskites; STEAM; METHANE; OXIDES; NI; PERFORMANCE; SYNGAS; METAL; GAS;
D O I：
10.1002/ceat.202100285
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Autothermal reforming (ATR) of acetic acid (HOAc) is a promising and alternative route for hydrogen production from renewable resources, but catalyst deactivation caused by cobalt metal sintering and coking is a major concern in ATR. In this work, perovskite-like catalysts of the formula SrxTi1-xCoO3 +/-delta (x = 0, 0.2, 0.5, and 0.8) were prepared by evaporation-induced self-assembly and then evaluated in ATR for hydrogen production. The SrxTi1-xCoO3 +/-delta catalysts exhibited high activity and stability as well as 100 % conversion of HOAc. Additionally, the Co particles with strong metal-support interaction of SrTi(Co)O-3 inhibited coking and agglomeration, and showed potential for hydrogen production by the ATR process.
引用
收藏
页码：1870 / 1876
页数：7
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