Dipyridine[5,10,15,20-tetrakis(4-carboxyphenyl)porphyrinato] cobalt(II) pyridine tetrasolvate monohydrate hydrate

被引:7
|
作者
Li, Zong-Sheng [1 ]
Chai, Jian-She [1 ]
机构
[1] Capital Univ Econ & Business, Coll Safety & Environm Engn, Beijing 100070, Peoples R China
关键词
D O I
10.1107/S1600536807015061
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Co(C48H28N4O8)( C5H5N) 2]center dot 4C(5)H(5)N center dot-H2O, the Co atom lies on a fourfold inversion axis, with the N atom and one C atom of the axial pyridine ligand on a twofold axis. Four pyridine solvent molecules hydrogen bond to the carboxylate groups of the porphyrin. The structure generates a hydrophobic void that incorporates a disordered solvent water molecule whose O atom lies on another fourfold inversion axis.
引用
收藏
页码:M1533 / M1535
页数:3
相关论文
共 50 条
  • [1] Supramolecular hydrogen bonding of [5,10,15,20-tetrakis(4-carboxyphenyl) porphyrinato] palladium(II) in the presence of competing solvents
    Lipstman, Sophia
    Goldberg, Israel
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2008, 64 : M53 - M57
  • [2] [5,10,15,20-Tetrakis(2,6-dimethoxyphenyl)porphyrinato]zinc(II) dichloromethane tetrasolvate
    Conrad, Diane
    DeCoskey, Jennifer
    Mock, Samantha
    Noll, Bruce C.
    Petrovic, Jelena
    Zovinka, Edward P.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M3058 - U1802
  • [3] 5,10,15,20-Tetrakis[4-(hexyloxy)phenyl] porphyrinato} nickel(II)
    Wang, Yu-Fang
    Zhao, Hong-Bin
    Chen, Liang
    Yang, De-Liang
    Wang, Bang-Ying
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M814 - +
  • [4] {5,10,15,20-Tetrakis[4-(octyloxy)phenyl]porphyrinato}copper(II)
    Yang, De-Liang
    Zhao, Hong-Bin
    Liao, Jun-Xu
    Chen, Liang
    Wang, Bang-Ying
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1673 - U1726
  • [5] [5,10,15,20-Tetrakis(2-thienyl)-porphyrinato]zinc(II)
    Purushothaman, B
    Varghese, B
    Bhyrappa, P
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2001, 57 (03) : 252 - 253
  • [6] [5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinato]iron(II) benzene disolvate
    Oh, Y
    Shin, BC
    Swenson, D
    Goff, HM
    Kang, SK
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 : M57 - M59
  • [7] [5,10,15,20-Tetrakis(4-chlorophenyl)porphyrinato]bis(tributylphosphine)cobalt(III) perchlorate
    Etemadi, Bijan
    Kia, Reza
    Asadi, Mozzafar
    Mohammadi, Kh.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M698 - U934
  • [8] Application of 5,10,15,20-tetrakis(4-carboxyphenyl)porphine for cadmium preconcentration in flow-injection system
    Kilian, K
    Pyrzynska, K
    ANALYTICAL SCIENCES, 2002, 18 (05) : 571 - 574
  • [9] Application of 5,10,15,20-Tetrakis(4-carboxyphenyl)porphine for Cadmium Preconcentration in Flow-Injection System
    Krzysztof Kilian
    Krystyna Pyrzynska
    Analytical Sciences, 2002, 18 : 571 - 574
  • [10] Insight into efficient bifunctional catalysis: Oxygen reduction and oxygen evolution reactions using MWCNTs based composites with 5,10,15,20-tetrakis(3′,5′-dimethoxyphenyl) porphyrinato cobalt(II) and 5,10,15,20-tetrakis(3′,5′-dihydroxyphenyl)porphyrinato cobalt(II)
    Yadav, Mamta
    Sonkar, Piyush Kumar
    Prakash, Kamal
    Ganesan, Vellaichamy
    Sankar, Muniappan
    Yadav, Dharmendra Kumar
    Gupta, Rupali
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2020, 45 (16) : 9710 - 9722