Chiral bidentate N-heterocyclic carbene complexes of Rh and Pd

被引：20
|
作者：
Ren, L [1 ]
Chen, AC [1 ]
Decken, A [1 ]
Crudden, CM [1 ]
机构：
[1] Univ New Brunswick, Dept Chem, Fredericton, NB E3B 6E2, Canada
来源：
CANADIAN JOURNAL OF CHEMISTRY | 2004年 / 82卷 / 12期
关键词：
chiral N-heterocyclic carbene; rhodium; palladium; oxazolidine; asymmetric catalysis;
D O I：
10.1139/V04-165
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of a new chiral, bidentate oxazoline/imidazolidene carbene precursor is described. This species is reacted with various metal salts in the presence of a base to generate rhodium and palladium complexes, which are characterized spectroscopically and crystallographically.
引用
收藏
页码：1781 / 1787
页数：7
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