Fe3O4 NANOPARTICLES AS AN EFFICIENT AND MAGNETICALLY RECOVERABLE CATALYST FOR FRIEDEL-CRAFTS ACYLATION REACTION IN SOLVENT-FREE CONDITIONS

被引：40

作者：

Hoseini, S. Jafar ^{[1
]}

Nasrabadi, Hasan ^{[1
]}

Azizi, Mahboobeh ^{[1
]}

Beni, Alireza Salimi ^{[1
]}

Khalifeh, Reza ^{[2
]}

机构：

[1] Univ Yasuj, Dept Chem, Fac Sci, Yasuj 74831, Iran

[2] Shiraz Uunivers Technol, Dept Chem, Shiraz, Iran

来源：

SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 12期

关键词：

Catalyst; Fe3O4; nanoparticles; Friedel-Crafts acylation; heterogenous catalysts; solvent free; IRON-OXIDE;

D O I：

10.1080/00397911.2012.663048

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Application of Fe3O4 nanoparticles (NPs) as a robust, very efficient, and magnetically recoverable catalyst was investigated in Friedel-Crafts acylation (FCA) of ferrocene and aromatic compounds. This reaction was performed with acid chlorides in solvent-free conditions at room temperature. The catalyst was easily separated by an external magnetic field from the reaction mixture. The separated catalyst was recycled for several consecutive runs without appreciable loss of its catalytic activity.

引用

页码：1683 / 1691

页数：9

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