Stereoregular silicon-containing polymers

被引：0

作者：

Kawakami, Y ^{[1
]}

机构：

[1] Japan Adv Inst Sci & Technol, Grad Sch Mat Sci, Tatsunokuchi, Ishikawa 9231292, Japan

来源：

POLYMERS FOR ADVANCED TECHNOLOGIES | 2001年 / 12卷 / 11-12期

关键词：

polyaddition; poly(carbosilane); poly(carbosiloxane); isotacticity; optical activity;

D O I：

10.1002/pat.85

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Optically active (R)-methylphenylpropargylsilane and (S)-2-(1-naphthyl)-2-phenyl-5,5-dimethyl-1-oxa-2,5-disilacyclopentane were prepared, and stereoregular and optically active polymers were obtained via hydrosilylation or ring-opening polymerization. Both polymerization reactions proceeded stereoselectively, and the tacticity of the polymers reflected the optical purity of the monomers. Copyright (C) 2001 John Wiley Sons, Ltd.

引用

页码：658 / 664

页数：7

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