Stereoregular silicon-containing polymers

被引：0

作者：

Kawakami, Y ^{[1
]}

机构：

[1] Japan Adv Inst Sci & Technol, Grad Sch Mat Sci, Tatsunokuchi, Ishikawa 9231292, Japan

来源：

POLYMERS FOR ADVANCED TECHNOLOGIES | 2001年 / 12卷 / 11-12期

关键词：

polyaddition; poly(carbosilane); poly(carbosiloxane); isotacticity; optical activity;

D O I：

10.1002/pat.85

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Optically active (R)-methylphenylpropargylsilane and (S)-2-(1-naphthyl)-2-phenyl-5,5-dimethyl-1-oxa-2,5-disilacyclopentane were prepared, and stereoregular and optically active polymers were obtained via hydrosilylation or ring-opening polymerization. Both polymerization reactions proceeded stereoselectively, and the tacticity of the polymers reflected the optical purity of the monomers. Copyright (C) 2001 John Wiley Sons, Ltd.

引用

页码：658 / 664

页数：7

共 50 条

[21] Synthesis and modification of silicon-containing polymers using ultrasound
Price, Gareth J.
POLYMER INTERNATIONAL, 2009, 58 (03) : 290 - 295
[22] Structures and photophysical properties of silicon-containing phenyleneethynylene polymers
Li, H
West, R
MACROMOLECULES, 1998, 31 (09) : 2866 - 2871
[23] ELECTRONIC-STRUCTURES OF SILICON-CONTAINING POLYMERS WITH UNSATURATED BONDS
TANAKA, K
KOBAYASHI, H
KOIKE, T
YAMABE, T
OSAWA, Y
NIWA, S
YASUDA, N
SYNTHETIC METALS, 1988, 25 (03) : 289 - 298
[24] Silicon-containing hyperbranched polymers via bimolecular polymerization.
Dvornic, PR
Hu, J
Meier, DJ
Nowak, RM
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U415 - U416
[25] Various silicon-containing polymers with Si(H)-CC units
Itoh, M
Iwata, K
Ishikawa, JI
Sukawa, H
Kimura, H
Okita, K
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2001, 39 (15) : 2658 - 2669
[26] Silicon-containing heterocyclic polymers and thin films made therefrom
Hamciuc, Corneliu
Hamciuc, Elena
Pakula, Tadeusz
Okrasa, Lidia
Journal of Applied Polymer Science, 2006, 102 (03): : 3062 - 3068
[27] AB-INITIO CALCULATIONS ON SILICON-CONTAINING CONJUGATED POLYMERS
BAKHSHI, AK
SOLID STATE COMMUNICATIONS, 1993, 88 (05) : 401 - 403
[28] New silicon-containing iron organometallic monomers and polymers.
Apodaca, P
Rahimian, K
Cervantes-Lee, F
Pannell, KH
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U1409 - U1409
[29] SILICON-CONTAINING POLYMERS DERIVED FROM MONO AND DISUBSTITUTED CYCLOPHOSPHAZENES
VANDEGRAMPEL, JC
VANDEGRAMPEL, RD
HENDRIKS, RHJ
JEKEL, AP
MEETSMA, A
VELDMAN, EGM
WUBBELS, JH
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1994, 93 (1-4): : 273 - 276
[30] Microlithographic applications of silicon-containing polymers and individual organosilicon compounds
Babich, ED
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 215 : U443 - U443

← 1 2 3 4 5 →