Syntheses and structures of [Et4N]2[Sn(dmit)3] and [Pb(dmit)(DMF)]n (dmit=2-thioxo-1,3-dithiole-4,5-dithiolato)

被引：11
|
作者：
Sheng, TL [1 ]
Wu, XT [1 ]
Lin, P [1 ]
Wang, QM [1 ]
Zhang, WJ [1 ]
Chen, L [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 1999年 / 48卷 / 02期
基金：
美国国家科学基金会;
关键词：
metal-dmit complexes; tin; lead; X-ray structure;
D O I：
10.1080/00958979908027959
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two complexes, [Et4N](2)[Sn(dmit)(3)], 1, and [Pb(dmit)(DMF)](n), 2, have been obtained and their structures crystallographically determined. In complex 1, the Sn atom is six-coordinated to six sulfur atoms from three dmit ligands; the anions form a one-dimensional network through S ... S contacts shorter than 3.7 Angstrom. Complex 2 forms a two-dimensional polymer, achieved through Pb atom coordinating not only to the chelating sulfur atoms of the dithiolate fragment of dmit, but also to the sulfur atom of the thiocarbonyl group of a dmit ligand. In complex 2, the central Pb atom is six-coordinated by four sulfur atoms from dmit ligands and two oxygen atoms of N,N-dimethylformamide ligands, exhibiting a distorted octahedral structure.
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收藏
页码：113 / 123
页数：11
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