Dehydrofluorination of hydrofluorocarbons by titanium alkylidynes via sequential C-H/C-F bond activation reactions. A synthetic, structural, and mechanistic study of 1,2-CH bond addition and β-fluoride elimination

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Department of Chemistry, Molecular Structure Center, Indiana University, Bloomington, IN 47405, United States ^{[1
]}

不详 ^{[2
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Organometallics | 1600年 / 1卷 / 331-347期

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摘要：

Titanium compounds

引用

共 9 条

[1] Dehydrofluorination of Hydrofluorocarbons by Titanium Alkylidynes via Sequential C-H/C-F Bond Activation Reactions. A Synthetic, Structural, and Mechanistic Study of 1,2-CH Bond Addition and β-Fluoride Elimination
Fout, Alison R.
Scott, Jennifer
Miller, Deanna L.
Bailey, Brad C.
Pink, Maren
Mindiola, Daniel J.
ORGANOMETALLICS, 2009, 28 (01) : 331 - 347
[2] Competing C-H and C-F bond activation reactions of a fluorinated olefin at Rh: a fluorido vinylidene complex as an intermediate in an unprecedented dehydrofluorination step
Talavera, Maria
Braun, Thomas
CHEMICAL SCIENCE, 2022, 13 (04) : 1130 - 1135
[3] C-F Bond Cleavage Enabled Redox-Neutral [4+1] Annulation via C-H Bond Activation
Wang, Cheng-Qiang
Ye, Lu
Feng, Chao
Loh, Teck-Peng
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (05) : 1762 - 1765
[4] Understanding intermolecular C-F bond activation by a transient titanium neopentylidyne: experimental and theoretical studies on the competition between 1,2-CF bond addition and [2+2]-cycloaddition/β-fluoride elimination
Fan, Hongjun
Fout, Alison R.
Bailey, Brad C.
Pink, Maren
Baik, Mu-Hyun
Mindiola, Daniel J.
DALTON TRANSACTIONS, 2013, 42 (12) : 4163 - 4174
[5] Mechanistic Study of Ru-NHC-Catalyzed Hydrodefluorination of Fluoropyridines: The Influence of the NHC on the Regioselectivity of C-F Activation and Chemoselectivity of C-F versus C-H Bond Cleavage
McKay, David
Riddlestone, Ian M.
Macgregor, Stuart A.
Mahon, Mary F.
Whittlesey, Michael K.
ACS CATALYSIS, 2015, 5 (02): : 776 - 787
[6] DFT study on ruthenium-catalyzed N-methylbenzamide-directed 1,4-addition of the ortho C-H bond to maleimide via C-H/C-C activation
Wu, Zi-Hao
Fang, De-Cai
ORGANIC CHEMISTRY FRONTIERS, 2022, 9 (24) : 6808 - 6816
[7] Nickel-Catalyzed Functionalization Reactions Involving C-H Bond Activation via an Amidate-Promoted Strategy and Its Extension to the Activation of C-F, C-O, C-S, and C-CN Bonds
Chatani, Naoto
ACCOUNTS OF CHEMICAL RESEARCH, 2023, 56 (21) : 3053 - 3064
[8] Synthetic, structural, and mechanistic studies of the C-H bond activation of phenols by W(PMe3)6 and W(PMe3)4(η2-CH2PMe2)H
1600, (114):
[9] SYNTHETIC, STRUCTURAL, AND MECHANISTIC STUDIES OF THE C-H BOND ACTIVATION OF PHENOLS BY W(PME3)6 AND W(PME3)4(ETA-2-CH2PME2)H
RABINOVICH, D
ZELMAN, R
PARKIN, G
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (12) : 4611 - 4621

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