IONIC CONDUCTIVITIES OF MX-K(OR RB)X-CSX-BAX(2) GLASSES (M=LI, CU OR AG, X=CL, BR OR I) COMPOSED OF SINGLE-X

被引：0
|
作者：
KAWAMOTO, Y [1 ]
KANNO, R [1 ]
OGURA, K [1 ]
SHOJIYA, M [1 ]
KADONO, K [1 ]
TANAKA, H [1 ]
机构：
[1] OSAKA NATL RES INST,DEPT OPT MAT,IKEDA,OSAKA 563,JAPAN
来源：
PHYSICS AND CHEMISTRY OF GLASSES | 1994年 / 35卷 / 05期
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D O I：
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
For the recently developed MX-K(or Rb)X-Cs-BaX(2) glasses (M=Li, Cu or Ag; X=C1, Br or I) the compositional dependence of ionic conductivity has been examined. In the M species dependence examined for 55MBr.20KBr.20CsBr.5BaBr(2) glasses (M=Li, Cu or Ag) the conductivity increases in the order of M=Li, Cu and Ag. In the X species dependence examined for 55LiX.20KX.20CsX.5BaX(2), 55CuX.24K (or Rb) X.6CsX.15BaX(2) and 55AgX.20KX.20CsX.5BaX(2) glasses the conductivity of the LiX and AgX based glasses increases in the order of X=Cl, Br and I, while the conductivity of the CuX based glasses increases in the order of X=I Br and C1. The most conductive glass in the examined series is a 55CuCl.24KCl.6CsCl.15BaCl(2) glass. These results are discussed from the standpoint of the local structures of MX components.
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页码：216 / 218
页数：3
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